Analysis of Sr2Mg (BO3)2Tb3+ Green Emitting Phosphor for Solid State Lighting: Implication for Light Emitting Diode (LED)

Vishal R Panse, Gaurav Rahate, Antomi Saregar, Manmeet Kaur, Aparna Dixit

Abstract


With the assist of  customized step wise combustion synthesis method Sr2Mg(BO3)2: Tb3+  phosphors were synthesize along with the luminescent proprieties, XRD, chromaticity coordinates with effect of emission intensity with related with the corresponding concentration were studied. The emission spectrum of Sr2Mg(BO3)2  :Tb3+ (x=0.2 to 2 mol %) excited by 353 nm exhibits a strong green emission among peak location at 546 nm is recognized to F-F transitions of Tb3+ 5D4-7F5 ion. This study suggest that Sr2Mg(BO3)2: Tb3+ phosphor be a prominent material as a green constituent for phosphor- transformed W-LEDs  for SSL

Keywords


Photoluminescence; XRD; SEM; CIE

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References


J. Zheng, C. Guo, X. Ding, Z. Ren, and J. Bai, “Enhanced luminescence of Tb 3+ by efficient energy transfer from Ce 3+ in Sr 2B 5O 9Cl host,” Curr. Appl. Phys., vol. 12, no. 3, pp. 643–647, 2012, doi: 10.1016/j.cap.2011.09.012.

A. Lakshmanan, R. S. Bhaskar, P. C. Thomas, R. S. Kumar, V. S. Kumar, and M. T. Jose, “A red phosphor for nUV LED based on (Y,Gd)BO3:Eu3+,” Mater. Lett., vol. 64, no. 16, pp. 1809–1812, 2010, doi: 10.1016/j.matlet.2010.05.034.

V. R. Panse, A. shukla, and S. J. Dhoble, “Luminescence investigation of microcrystalline Ca2PO4Cl:Dy3+ phosphor for eco friendly solid state lighting,” Optik (Stuttg)., vol. 130, pp. 539–542, 2017, doi: 10.1016/j.ijleo.2016.10.094.

N. S. Bajaj and S. K. Omanwar, “Combustion synthesis and characterization of phosphor KSr4 (BO3)3:Dy3+,” Opt. Mater. (Amst)., vol. 35, no. 6, pp. 1222–1225, 2013, doi: 10.1016/j.optmat.2013.01.025.

V. R. Panse, N. S. Kokode, K. N. Shinde, and S. J. Dhoble, “Luminescence in microcrystalline green emitting Li2Mg1−xZrO4:xTb3+ (0.1 ≤ x ≤ 2.0) phosphor,” Results Phys., vol. 8, pp. 99–103, 2018, doi: 10.1016/j.rinp.2017.10.025.

V. R. Panse, A. N. Yerpude, S. J. Dhoble, N. S. Kokode, and R. Choithrani, “Synthesis and optical characterization of CaSr2Al2O6:RE3+(RE = Eu and Tb) phosphor for solid state lighting,” J. Mater. Sci. Mater. Electron., vol. 28, no. 22, pp. 16880–16887, 2017, doi: 10.1007/s10854-017-7606-y.

A. N. Yerpude, V. R. Panse, S. J. Dhoble, N. S. Kokode, and M. Srinivas, “Photoluminescence properties of Ca2Al2O5:RE3+ (RE = Eu, Dy and Tb) phosphors for solid state lighting,” Luminescence, vol. 32, no. 7, pp. 1361–1364, 2017, doi: 10.1002/bio.3340.

R. L. Kohale and S. J. Dhoble, “Development of Dy3+ activated K2MgP2O 7 pyrophosphate phosphor for energy saving lamp,” J. Lumin., vol. 138, pp. 153–156, 2013, doi: 10.1016/j.jlumin.2013.02.007.

V. R. Panse, A. Shukla, S. V. Panse, N. S. Dhoble, and S. J. Dhoble, “Preparation and tunable luminescence of microcrystalline SrMg2Al16O27:Tb3+ and Eu3+ phosphor for solid state lighting,” J. Mater. Sci. Mater. Electron., vol. 28, no. 2, pp. 2193–2199, 2017, doi: 10.1007/s10854-016-5785-6.

H. A. A. Seed Ahmed, O. M. Ntwaeaborwa, and R. E. Kroon, “High efficiency energy transfer in Ce,Tb co-doped silica prepared by sol-gel method,” J. Lumin., vol. 135, pp. 15–19, 2013, doi: 10.1016/j.jlumin.2012.10.037.

S. C. Gedam, S. J. Dhoble, and S. V. Moharil, “Luminescence in Ce3+ doped mixed sulphate fluoride phosphors [NaMgSO4F and Na3SO4F],” Eur. Phys. J. Appl. Phys., vol. 184, no. 3, pp. 177–184, 2006, doi: 10.1051/epjap.

V. R. Panse, N. S. Kokode, A. N. Yerpude, and S. J. Dhoble, “Combustion synthesis of Sr2B2O5:Tb3+ green emitting phosphor for solid state lighting,” Optik (Stuttg)., vol. 127, no. 4, pp. 1603–1606, 2016, doi: 10.1016/j.ijleo.2015.11.030.

V. Natarajan, A. R. Dhobale, and C. H. Lu, “Preparation and characterization of tunable YVO4: Bi3+, Sm3+ phosphors,” J. Lumin., vol. 129, no. 3, pp. 290–293, 2009, doi: 10.1016/j.jlumin.2008.10.001.

L. Y. Zhou, J. S. Wei, J. X. Shi, M. L. Gong, and H. Bin Liang, “A novel green phosphor GdCaAlO4:Tb3+ for PDP application,” J. Lumin., vol. 128, no. 8, pp. 1262–1266, 2008, doi: 10.1016/j.jlumin.2007.12.030.

J. K. Sheu et al., “White-light emission from near UV InGaN-GaN LED chip precoated with blue/green/red phosphors,” IEEE Photonics Technol. Lett., vol. 15, no. 1, pp. 18–20, 2003, doi: 10.1109/LPT.2002.805852.

R. R. Patil and S. V. Moharil, “Cu+ Luminescence in New Hosts,” Phys. Status Solidi Appl. Res., vol. 187, no. 2, pp. 557–562, 2001, doi: 10.1002/1521-396X(200110)187:2<557::AID-PSSA557>3.0.CO;2-2.

N. S. Kokode, V. R. Panse, and S. J. Dhoble, “Synthesis and optical characterization of Ca2PO4Cl: Tb3+ and Mn2+ phosphor for solid state lighting,” Adv. Mater. Lett., vol. 6, no. 7, pp. 616–619, 2015, doi: 10.5185/amlett.2015.SMS3.

V. R. Panse, N. S. Kokode, and S. J. Dhoble, “Preparation and luminescence properties of Tb3+ activated microcrystalline ZrO2 green emitting phosphor for solid state lighting,” Optik (Stuttg)., vol. 126, no. 23, pp. 4782–4787, 2015, doi: 10.1016/j.ijleo.2015.07.062.

M. H. Weng, R. Y. Yang, Y. M. Peng, and J. L. Chen, “Yellowish green-emitting KSrPO 4:Tb 3+ phosphors with various doping concentrations prepared by using microwave assisted sintering,” Ceram. Int., vol. 38, no. 2, pp. 1319–1323, 2012, doi: 10.1016/j.ceramint.2011.09.007.

L. Zhu, A. Lu, C. Zuo, and W. Shen, “Photoluminescence and energy transfer of Ce3+ and Tb 3+ doped oxyfluoride aluminosilicate glasses,” J. Alloys Compd., vol. 509, no. 29, pp. 7789–7793, 2011, doi: 10.1016/j.jallcom.2011.04.154.

A. Setiawan, E. K. Palupi, R. Umam, H. Alatas, and Irzaman, “Optical characterization of Ba0.5Sr0.5TiO3 material grown on a p-type silicon substrate (111) doped niobium oxide and chlorophyll,” Ferroelectrics, vol. 568, no. 1, pp. 62–70, 2020, doi: 10.1080/00150193.2020.1735893.

E. K. Palupi et al., “Analysis of Spectroscopy: Mustard Greens Leaf of Chlorophyll as a Ba0.2Sr0.8TiO3 (Barium Strontium Titanate) Film Dopant,” Integr. Ferroelectr., vol. 201, no. 1, pp. 75–85, 2019, doi: 10.1080/10584587.2019.1668692.

A. N. Yerpude, V. V Shimde, V. R. Anse, S. J. Dhoble, and N. S. Kokode, “PHOSPHOR FOR GREEN LIGHTING TECHNOLOGY,” Int. J. Curr. Eng. Sci. Res., vol. 5, no. 1, pp. 28–30, 2018.

E. K. Palupi et al., “Micro-Raman analysis of Ba0.2Sr0.8TiO3 (barium strontium titanate) doped of chlorophyll of cassava leaf,” Ferroelectrics, vol. 540, no. 1, pp. 227–237, 2019, doi: 10.1080/00150193.2019.1611116.




DOI: http://dx.doi.org/10.24042/ijecs.v1i1.9334

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